Sania and Raina were down 1-8 in the Super Tie break but reeled off seven straight points to make it 8-8 but lost the next two points to make an exit from the Games.
Sania will now become the first female athlete to represent India at four Olympics when she features at the Tokyo 2020, slated to get underway from July 23 while Ankita Raina will be making her debut at the showpiece event.